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|Section2= |Section7= |Section8= }} Sulfur chloride pentafluoride is an inorganic compound with the formula . It exists as a colorless gas at room temperature and is highly toxic, like most compounds containing the pentafluorosulfide (SF5) functional group.〔Nyman, F., Roberts, H. L., Seaton, T. "Sulfur Chloride Pentafluoride" Inorganic Syntheses, 1966, Volume 8, p. 160. 〕 The compound adopts an octahedral geometry with symmetry. Sulfur chloride pentafluoride is the only commercially available reagent for adding the group to organic compounds.〔 ==Reactivity== In contrast to the high reactivity and toxicity of , sulfur hexafluoride (), is inert and nontoxic despite having a closely related chemical formula. This difference highlights the lability of the S-Cl bond in this molecule. Under free-radical conditions, adds across double bonds. The following reaction involves the reaction of propene: : + → CH3CH(Cl)CH2SF5 The addition reaction is catalyzed by at around -30 °C. is used similarly. is also a precursor to O(SF5)2 and F2NSF5 (from tetrafluorohydrazine). 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Sulfur chloride pentafluoride」の詳細全文を読む スポンサード リンク
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