翻訳と辞書
Words near each other
・ Suliman Bashear
・ Sulfoxide
・ Sulfoxone
・ Sulfozinum
・ Sulfur
・ Sulfur (band)
・ Sulfur (disambiguation)
・ Sulfur (magazine)
・ Sulfur (song)
・ Sulfur assimilation
・ Sulfur bacteria
・ Sulfur bromide
・ Sulfur butterfly
・ Sulfur carrier protein ThiS adenylyltransferase
・ Sulfur chloride
Sulfur chloride pentafluoride
・ Sulfur concrete
・ Sulfur cycle
・ Sulfur dibromide
・ Sulfur dichloride
・ Sulfur difluoride
・ Sulfur diimide
・ Sulfur dioxide
・ Sulfur dioxygenase
・ Sulfur dye
・ Sulfur fluoride
・ Sulfur hexafluoride
・ Sulfur hexafluoride circuit breaker
・ Sulfur lamp
・ Sulfur metabolism


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

Sulfur chloride pentafluoride : ウィキペディア英語版
Sulfur chloride pentafluoride

|Section2=
|Section7=
|Section8=
}}
Sulfur chloride pentafluoride is an inorganic compound with the formula . It exists as a colorless gas at room temperature and is highly toxic, like most compounds containing the pentafluorosulfide (SF5) functional group.〔Nyman, F., Roberts, H. L., Seaton, T. "Sulfur Chloride Pentafluoride" Inorganic Syntheses, 1966, Volume 8, p. 160. 〕 The compound adopts an octahedral geometry with symmetry. Sulfur chloride pentafluoride is the only commercially available reagent for adding the group to organic compounds.〔
==Reactivity==
In contrast to the high reactivity and toxicity of , sulfur hexafluoride (), is inert and nontoxic despite having a closely related chemical formula. This difference highlights the lability of the S-Cl bond in this molecule.
Under free-radical conditions, adds across double bonds. The following reaction involves the reaction of propene:
: + → CH3CH(Cl)CH2SF5
The addition reaction is catalyzed by at around -30 °C. is used similarly.
is also a precursor to O(SF5)2 and F2NSF5 (from tetrafluorohydrazine).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Sulfur chloride pentafluoride」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.